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HL Paper 1

The graph shows values of ΔG for a reaction at different temperatures.

Which statement is correct?

A.     The standard entropy change of the reaction is negative.

B.     The standard enthalpy change of the reaction is positive.

C.     At higher temperatures, the reaction becomes less spontaneous.

D.     The standard enthalpy change of the reaction is negative.




The graph shows Gibbs free energy of a mixture of N2O4 (g) and NO2 (g) in different proportions.

N2O4 (g)  2NO2 (g)

Which point shows the system at equilibrium?




A mixture of 0.40 mol of CO (g) and 0.40 mol of H2 (g) was placed in a 1.00 dm3 vessel. The following equilibrium was established.

CO (g) + 2H2 (g)  CH3OH (g)

At equilibrium, the mixture contained 0.25 mol of CO (g). How many moles of H(g) and CH3OH (g) were present at equilibrium?




Components X and Y are mixed together and allowed to reach equilibrium. The concentrations of X, Y, W and Z in the equilibrium mixture are 4, 1, 4 and 2 mol d m 3  respectively.

X + 2Y 2W + Z

What is the value of the equilibrium constant, Kc?

A.     1 8

B.     1 2

C.     2

D.     8




Which statement is correct for a spontaneous reaction?




At 700 ºC, the equilibrium constant, Kc, for the reaction is 1.075 × 108.

2H2 (g) + S2 (g) 2H2S (g)

Which relationship is always correct for the equilibrium at this temperature?

A. [H2S]2 < [H2]2 [S2]

B. [S2] = 2[H2S]

C. [H2S] < [S2]

D. [H2S]2 > [H2]2[S2]




1.0 mol of N2(g), 1.0 mol of H2(g) and 1.0 mol of NH3(g) are placed in a 1.0 dm3 sealed flask and left to reach equilibrium. At equilibrium the concentration of N2(g) is 0.8 mol dm−3.

N2(g) + 3H2(g) 2NH3(g)

What are the equilibrium concentration of H2(g) and NH3(g) in mol dm−3?

M18/4/CHEMI/HPM/ENG/TZ1/23




1.0 mol each of sulfur dioxide, oxygen, and sulfur trioxide are in equilibrium.

2SO2(g)+O2(g)2SO3(g)

Which change in the molar ratio of reactants will cause the greatest increase in the amount of sulfur trioxide?

Assume volume and temperature of the reaction mixture remain constant.




Which combination describes the system at equilibrium?

 




Which is correct for a reaction with a positive change in Gibbs free energy, ΔGθ?

A. The formation of reactants is favoured.

B. The formation of products is favoured.

C. The reaction is at equilibrium.

D. The reaction is spontaneous.




Which is correct for a redox reaction where the standard electrode potential is negative?

ΔGΘ = −nFEΘ and ΔGΘ = −RT ln K

 

A.   ΔGΘ is negative and K is less than 1.

B.   ΔGΘ is negative and K is greater than 1.

C.   ΔGΘ is positive and K is less than 1.

D.   ΔGΘ is positive and K is greater than 1.




Iodine and bromine gases were mixed and allowed to reach equilibrium.

What is the value of the equilibrium constant?

A. 0.05

B. 1

C. 4

D. 10




Which corresponds to a system at equilibrium?